Atomic Theories Quantum Mechanical Model Valence Bond Theory

Atomic Theories Quantum Mechanical Model Valence Bond Theory

Atomic Theories

Atomic Theories Quantum Mechanical Model Valence Bond Theory Coordination Compounds

Atomic Theory, Coordination compounds and Solubility product

Topics for test

Quantum mechanical model of the atom

Chapter 8

  • Electromagnetic radiation
    • Relation between frequency, wavelength and energy
  • Line spectra of hydrogen
  • The Rydberg equation
    • Calculation of wavelength
  • Bohr Theory
  • Wave mechanical model
  • Quantization of energy of an electron
  • Quantum numbers
    • Principal
    • Angular momentum
    • Magnetic moment
    • Spin
    • Pauli’s exclusion principle
    • Paramagnetism, Diamagnetism
    • Ground state configurations
    • Excited state configurations
    • Abbreviated electron configuration – Aufbau order
    • Electronic configuration
      • Exceptional configuration
      • Regular configuration
    • Atomic orbitals and shapes, s,p,d; degeneracy, uncertainty principle
    • Hunds rule
  • Chemical Bonding
  • Covalent bonds
  • Ionic bonds
  • Explain shapes of molecules using Valence Bond Theory or Hybridization
  • Bonding in methane, ethane, ethane, ethane, ethyne etc. SF6, PCl5, CH4, BF3,BeCl2, NH4Cl,
  • Bonding polarity and electronegativity only application based on
    • Hydrogen bonds
    • Polar bonds
    • London’s Dispersion force
  • Shapes of molecules and its effect on properties of the compound
  • Hybrid orbitals and shapes
  • Sigma bonds, pi bonds
  • Bonding and anti-bonding molecular orbitals

 

Metal Complexes

Chapter 22 Wiley

  • Complex ions
  • Types of ligands
  • Writing formulas of metal complexes
  • Naming of metal complexes
  • Coordination number and shapes of complex compounds – use hybridization to explain bonding
  • Some common examples of complex ions in biological species
Solubility product

Chapter 18 Wiley

  • Equilibrium of sparing soluble salts
  • Solubility product constant Ksp
  • Determination of Ksp from molar solubility
  • Ion product Vs Solubility product
  • Determining molar solubility from Ksp
  • Common ion effect, qualitative explanation and calculation
  • Predicting precipitation, problems
  • Selective precipitation of halides, sulfides, hydroxides, metals
  • Application of knowledge of Ksp
  • Use of complex ion formation in qualitative analysis
  • Separation of metal ions using Ksp

 

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